JAM 2016 Syllabus For Chemistry (CY)

JAM 2016 Syllabus For Chemistry (CY):



Syllabus For JAM 2016:

  • Mathematics Statistics (MS)
  • Mathematics (MA)
  • Physics (PH)



Chemistry:


Physical Chemistry:



  • Basic Mathematical Concepts: Functions, maxima and minima, integrals, ordinary differential equations, vectors and matrices, determinants, elementary statistics and probability theory.


  • Atomic and Molecular Structure: Fundamental particles, Bohr’s theory of hydrogen-like atom; wave-particle duality; Uncertainty principle; Schrödinger’s wave equation; Quantum numbers, shapes of orbitals; Hund’s rule and Pauli’s exclusion principle, electronic configuration of simple homonuclear diatomic molecules.


  • Theory of Gases: Equation of state of ideal and non-ideal (van der Waals) gases, Kinetic theory of gases. Maxwell-Boltzmann distribution law; equipartition of energy.


  • Solid state: Crystals, crystal systems, X-rays, NaCl and KCl structures, close packing, atomic and ionic radii, radius ratio rules, lattice energy, Born-Haber cycle, isomorphism, heat capacity of solids.
  • Chemical Thermodynamics: Reversible and irreversible processes; First law and its application to ideal and nonideal gases; Thermochemistry; Second law; Entropy and free energy, Criteria for spontaneity.


  • Chemical and Phase Equilibria: Law of mass action; Kp, Kc, Kx and Kn; Effect of temperature on K; Ionic equilibria in solutions; pH and buffer solutions; Hydrolysis; Solubility product; Phase equilibria–Phase rule and its application to one-component and two-component systems; Colligative properties.


  • Electrochemistry: Conductance and its applications; Transport number; Galvanic cells; EMF and Free energy; Concentration cells with and without transport; Polarography; Concentration cells with and without transport; Debey-Huckel-Onsagar theory of strong electrolytes.


  • Chemical Kinetics: Reactions of various order, Arrhenius equation, Collision theory; Theory of absolute reaction rate; Chain reactions – Normal and branched chain reactions; Enzyme kinetics; photochemical processes; Catalysis.


  • Adsorption: Gibbs adsorption equation, adsorption isotherm, types of adsorption, surface area of adsorbents, surface films on liquids.



Organic Chemistry:


  • Basic Concepts in Organic Chemistry and Stereochemistry: Electronic effect (resonance, inductive, hyperconjugation) and steric effects and its applications (acid/base property). Optical isomerism in compounds without any stereocenters (allenes, biphenyls), conformation of acyclic systems (substituted ethane/npropane/n-butane) and cyclic systems (mono and di substituted cyclohexanes).


  • Organic Reaction Mechanism and Synthetic Applications: Chemistry reactive intermediates, carbine, nitrene, benzyne, Hofmann-Curtius-Lossen rearrangement, Wolf rearrangement, Simmons-Smith reaction, Reimer-Tiemann reaction, Michael reaction, Darzens reaction, Witting reaction, McMurry reaction. Pinacol-pinacolone, Favorskii, benzilic acid rearrangement, dienonc-phenol rearrangement, Bayer-Villeger reaction. Oxidation and reduction reactions in organic chemistry. Organometallic reagents in organic synthesis (Grignard and organocopper). Diels-Alder reaction, Sigmatropic reactions.


  • Qualitative Organic Analysis: Functional group interconversions, structural problems using chemical reactions, identification of functional groups by chemical tests, elementary 1H NMR and IR spectroscopy as a tool for structural elucidation.


  • Natural Products Chemistry: Introductory chemistry of alkaloids, terpenes, carbohydrates, amino acids, peptides and nucleic acids.


  • Heterocyclic Chemistry: Monocyclic compounds with one hetero atom.


Inorganic Chemistry:




  • Periodic Table: Periodic classification of elements and periodicity in properties; general methods of isolation and purification of elements.


  • Chemical Bonding and Shapes of Compounds: Types of bonding; VSEPR theory and shapes of molecules; hybridization; dipole moment; ionic solids; structure of NaCl, CsCl, diamond and graphite; lattice energy.


  • Main Group Elements (s and p blocks): Chemistry with emphasis on group relationship and gradation in properties; structure of electron deficient compounds of main group elements and application of main group elements.


  • Transition Metals (d block): Characteristics of 3d elements; oxide, hydroxide and salts of first row metals; coordination complexes; VB and Crystal Field theoretical approaches for structure, color and magnetic properties of metal complexes. Organometallic compounds, metal carnonyls, nitrosyls and metallocenes, ligands with back bonding capabilities; MO theory approaches to explain bonding in metal-carbonyl, metal-nitrosyl and metalphosphine complexes.


  • Bioinorganic Chemistry: Essentials and trace elements of life, basic reactions in the biological systems and the role of metal ions especially Fe2+, Fe3+, Cu2+ and Zn2+, function of hemoglobin and myoglobin.


  • Instrumental Methods of Analysis: Basic principles, instrumentations and simple applications of conductometry, potentiometry, UV-vis spectrophotometry, analysis of water, air and soil samples.


  • Analytical Chemistry: Principles of qualitative and quantitative analysis; acid-base, oxidation-reduction and EDTA and precipitation reactions; use of indicators; use of organic reagents in inorganic analysis; radioactivity; nuclear reactions; applications of isotopes.


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